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To make the buttermilk: Combine milk and vinegar in a bowl and set aside for 5 minutes to sour the milk.
Combine flour, sugar, baking powder, baking soda, and salt in a large mixing bowl.
Whisk egg, butter, and vanilla extract into buttermilk mixture until well combined; add flour mixture and whisk until just combined. Fold in chocolate chips. The pancake batter will be thick. Allow batter to rest for 5 minutes.
Heat a large skillet over medium-low heat, and coat with cooking spray.
Pour about ¼ cup of batter for each pancake onto the skillet. Cook until bubbles appear on the surface, 2 to 4 minutes. Flip pancake with a spatula, and cook until browned on the other side, 2 to 3 more minutes. Repeat with remaining batter. Serve immediately.
¾ cup milk
2 tablespoons white vinegar
1 cup all-purpose flour
2 tablespoons white sugar
1 teaspoon baking powder
½ teaspoon baking soda
¼ teaspoon salt
1 large egg
2 tablespoons unsalted butter, melted
1 teaspoon vanilla extract
½ cup mini chocolate chips, or more to taste
cooking spray